A polymer - zeolite composite for mixed metal removal from aqueous solution

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Yildiz Yigit M., Baran E. S., MORAL Ç.

WATER SCIENCE AND TECHNOLOGY, cilt.83, sa.5, ss.1152-1166, 2021 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 83 Sayı: 5
  • Basım Tarihi: 2021
  • Doi Numarası: 10.2166/wst.2021.057
  • Dergi Adı: WATER SCIENCE AND TECHNOLOGY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, PASCAL, Analytical Abstracts, Aqualine, Aquatic Science & Fisheries Abstracts (ASFA), BIOSIS, Biotechnology Research Abstracts, CAB Abstracts, Chimica, Compendex, EMBASE, Environment Index, Geobase, MEDLINE, Pollution Abstracts, Public Affairs Index, Veterinary Science Database, Directory of Open Access Journals
  • Sayfa Sayıları: ss.1152-1166
  • Anahtar Kelimeler: alginate, cadmium, clinoptilolite, copper, heavy metals, lead
  • Akdeniz Üniversitesi Adresli: Evet

Özet

Heavy metals become inevitable pollutants that are toxic to life. Lots of treatment methods are available; adsorption is a cheap option. Metals are mostly found as mixtures in wastewaters. Taking this into account, a natural composite adsorbent aims to remove multiple heavy metals (Pb2+, Cu2+, Cd2+). Alginate was combined with clinoptilolite to form alginate - clinoptilolite (A-C) beads. First, factors influencing the removal efficiency of metals were investigated. Then, continuous column experiments were performed to evaluate the real application potential of the adsorbent. A-C beads preferably adsorbed Pb2+. Batch experiments showed metal uptake reached equilibrium after 24 hours and kinetics were compatible with the first-order. Also, pH values near neutral levels were observed to increase heavy metal removal. On the other hand, adsorption equilibrium was well described by the Langmuir model for Cu2+ and Cd2+ and by the Freundlich model for Pb2+. The highest heavy metal uptake was calculated as 2,145 mg /g A-C beads for Pb2+. Continuous column operations were suggested to apply low flow rates (<2 mL/min) and heavy metal concentration (<10 mg/L) for effectiveness. A-C beads can be a good candidate for mixed heavy metal removal composed of environmentally friendly and low-cost materials.