Apparent molar volume and viscosity of compounds with asymmetric carbon atoms

Ayranci E.

JOURNAL OF CHEMICAL AND ENGINEERING DATA, cilt.42, sa.5, ss.934-937, 1997 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 42 Sayı: 5
  • Basım Tarihi: 1997
  • Doi Numarası: 10.1021/je970055p
  • Dergi Adı: JOURNAL OF CHEMICAL AND ENGINEERING DATA
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.934-937
  • Akdeniz Üniversitesi Adresli: Evet

Özet

Apparent molar volumes and viscosities of l- and meso-tartaric acid in water and of (1R,2S,5R)- and (1S,2R,5S)-menthyl p-toluenesulfinate in l-butanol at 25 degrees C are reported. The differences observed between E-and meso-forms of tartaric acid and between (1R,BS,5R)- and (1S,2R,5S)-forms of menthyl p-toluenesulfinates are interpreted in terms of structural differences arising from different configurations of isomeric compounds. The results support the conclusion that different forms of compounds with more than one asymmetric center show differences in solution behavior.